Natural Attenuation
Natural Attenuation is the degradation or dissipation
of a
contaminant plume through natural means. The major agent of
natural attenuation is bio-degradation, which is facilitated by
native bacteria. The activity of these bacteria is controlled by
the concentration of contaminants and by the presence of electron
acceptors, which allows the bacteria to oxidize or reduce the
contaminants. In real field conditions reduction may only occur
in rare cases. If the amount of electron acceptors at a site is
found to be sufficient to degrade the contamination before it can
endanger health or the environment, then nature can be left to
take care of the problem on its own. In order to do this safely;
it is necessary to have sufficient information
about the site to determine the risk.
The most effective hydrocarbon degraders (eaters) are
the
aerobic (oxygen using) bacteria. Usually, the factor controlling
the rate that these bacteria degrade the gasoline is the amount
of available dissolved oxygen.
A much slower degradation process starts when the
dissolved
oxygen is used up. The plume begins to become anaerobic and the
bacteria commence to reduce nitrate, ferric iron, and sulfate to
further degrade the hydrocarbons. Eventually, as these compounds
are used, the bacteria begin methogenesis, in which the
hydrocarbons are slowly converted to methane.
Natural Attenuation Study
In order to determine the site potential for natural
and
enhanced bioremediation, groundwater is sampled for the following
analyses:
- Dissolved Oxygen, O2
- Nitrate, NO3-
- Sulfate, SO42-
- Ferrous iron, Fe2+. The
actual electron acceptor is ferric iron Fe3+
but it is insoluble, so the reaction product Fe2+
is measured.
- TPHg/MBTEX
Additionally Air samples are collected and
tested for
O2, CO2, Methane, and TPHg/MBTEX concentrations.
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